Catalyst for elemental sulfur recovery process

U.S. Patent Number: 5384301

Abstract: A catalytic reduction process for the direct recovery of elemental sulfur from various SO.sub.2 -containing industrial gas streams. The catalytic process provides high activity and selectivity, as well as stability in the reaction atmosphere, for the reduction of SO.sub.2 to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over a metal oxide composite catalyst having one of the following empirical formulas: wherein FO.sub.2 is a fluorite-type oxide; RO represents an alkaline earth oxide; RO.sub.1.5 is a Group IIIB or rare earth oxide; Ln is a rare earth element having an atomic number from 57 to 65 or mixtures thereof; M is a transition metal or a mixture of transition metals; n is a number having a value from 0.0 to 0.35; k is a number having a value from 0.0 to about 0.5; and x is a number having a value from about 0.45 to about 0.55.

Inventors: Flytzani-Stephanopoulos; Maria (Winchester, MA), Liu; Wei (Cambridge, MA)

Assignee: Massachusetts Institute of Technology (Cambridge, MA)

Application Number: 08/097,367

Issued: 1995-01-24

Expired: 2007-01-24

Classes: 502/304 ; 423/244.06; 423/244.07; 423/263; 423/464; 502/302; 502/306; 502/313; 502/321; 502/326; 502/328; 502/339; 502/340; 502/347; 502/349; 502/353

Field of search: 502/303,304,340,345,302,306,313,321,326,328,339,347,349,353 423/244.06,244.07,593

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